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Author Notes:

Correspondence: Craig L. Hill chill@emory.edu This article was submitted to Inorganic Chemistry, a section of the journal Frontiers in Chemistry

KS and CH oversaw all writing. QY, DC-W, MT, YG all contributed to the writing of the WOC section. DM and TL provided input.

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

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Research Funding:

Funding. The multi-functional POM-based polymer work was funded by the Defense Threat Reduction Agency (grant # HDTRA1-16-1-0029), and the catalytic water oxidation work was funded by the U.S. Department of Energy, Office of Basic Energy Sciencies, Solar Photochemistry program (grant # DE-FG02-07ER15906).

Keywords:

  • Polyoxometalates (POMs)
  • heterogeneous catalysis
  • multi-functional polymers
  • catalytic water oxidation
  • photoelectrochemical water splitting

Multi-tasking POM systems

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Journal Title:

Frontiers in Chemistry

Volume:

Volume 6, Number AUG

Publisher:

Type of Work:

Article | Final Publisher PDF

Abstract:

Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.

Copyright information:

© 2018 Sullivan, Yin, Collins-Wildman, Tao, Geletii, Musaev, L2018-11-13ian and Hill.

This is an Open Access work distributed under the terms of the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0/).
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