About this item:

373 Views | 0 Downloads

Author Notes:

fmcdona@emory.edu

Subject:

Research Funding:

National Cancer Institute : NCI

This work was initially supported by the National Institutes of Health, grant CA-59703.

Brønsted Acid-Promoted Glycosylations of Disaccharide Glycal Substructures of the Saccharomicins

Tools:

Journal Title:

Organic Letters

Volume:

Volume 11, Number 21

Publisher:

, Pages 4850-4853

Type of Work:

Article | Post-print: After Peer Review

Abstract:

An acid-promoted glycosylation and alkynol cycloisomerization sequence provided direct access to the 2-deoxytrisaccharide corresponding to the fucose-saccharosamine-digitoxose substructure of saccharomicin B. In the course of this work, the absolute stereochemistry of the repeating fucose-saccharosamine disaccharide of saccharomicins was also confirmed.

Copyright information:

© 2009 American Chemical Society

Export to EndNote